出版日期：2023-08-25 00:00:00

著者：Yan-Ying Wu, Yi-Lin Wu, Cheng-Lan Lin, Hung-Cheng Chen, Yao-Yuan Chuang, Chih-Hsien Chen, Chih-Ming Chou

著錄名稱、卷期、頁數：Organic Letters 25(43), p.7763-7768

摘要：A strategy for the synthesis of dibenz[a,j]anthracenes (DBAs) from cyclohexa-2,5-diene-1-carboxylic acids is presented. Our approach involves sequential C–H olefination, cycloaddition, and decarboxylative aromatization. In the key step for DBA skeleton construction, the bis-C–H olefination products, 1,3-dienes, are utilized as substrates for [4 + 2] cycloaddition with benzyne. This concise synthetic route allows for regioselective ring formation and functional group introduction. The structural features and photophysical properties of the resulting DBA molecules are discussed.

語言：zh_TW

ISSN：1523-7060; 1523-7052

期刊性質：國外

收錄於：SCI EI

審稿制度：是

國別：USA

出版型式：電子版,紙本