出版日期：2006-12-05 00:00:00

著者：Wang, Shih-Chieh; Chen, Pao-cheng; Yeh, Jet-tao; Chen, Kan-nan

單位：淡江大學化學學系

出版者：John Wiley & Sons

著錄名稱、卷期、頁數：Journal of Applied Polymer Science 102(5), pp.4383-4393

摘要：An azetidine (AZT) containing compound, 3-azetidinyl propanol was synthesized from methyl acrylate with 3-amino-1-propanol in a four-step reaction. It was introduced into an isocyanate-terminated carboxylic acid containing polyurethane (PU) prepolymer as the end group. A single-component, AZT-terminated self-curable aqueous-based PU dispersion was obtained from the water dispersion process after it was neutralized with triethylamine. Its carboxylic groups served not only as the internal emulsifier stabilizing the aqueous PU dispersion but also as PU self-curing sites toward its AZT end groups via a ring-opening reaction. The curing reaction took place on drying and resulted in polymeric network structure formation among the polymers. The performance properties of this self-cured PU were evaluated in this study.

關鍵字：crosslinking; dispersions; functionalization of polymers; polyurethanes

ISSN：0021-8995

期刊性質：國外

收錄於：SCI