出版日期：2012-04-01 00:00:00

著者：Wang, Shih-Chieh; Chen, Po-Chen; Hwang, Jing-Zhong; Huang, Chi-Yuan; Yeh, Jen-Taut; Chen, Kan-Nan

單位：淡江大學化學學系 淡江大學化學工程與材料工程學系

出版者：Hoboken: John Wiley & Sons, Inc.

著錄名稱、卷期、頁數：Journal of Applied Polymer Science 124(1), pp.175–181

摘要：A mono-azetidine compound had been demonstrating a ring opening reaction with carboxylic acid (e.g., trimethylacetic acid, TMAA) and that resulted in an amino ester bond formation at ambient temperature. A triazetidine compound (trimethylolpropane tris(1-azetidinyl)propionate, TMPTA-AZT) was obtained via Michael addition of azetidine (AZT) to trimethylolpropane triacrylate (TMPTA). The carboxylic groups of anionic aqueous-based polyurethanes (PU) served as internal emulsifier, which stabilized PU dispersion and also served as PU curing sites. The triazetidine compound (TMPTA-AZT) was introduced into anionic aqueous-based PU dispersion as a new latent curing agent and that mixture became a single-component self-curable aqueous PU system. A crosslinked PU film was obtained from this PU system on drying at ambient temperature. The final polymer performance properties demonstrated the crosslinking behaviors of this new curing agent, TMPTA-AZT, with carboxylic ion-containing aqueous-based PU resins.

關鍵字：self-curing; azetidine; ring-opening; aqueous-based PU; Michael addition

語言：en

ISSN：1097-4628

期刊性質：國外

收錄於：SCI

通訊作者：陳幹男 (knchen@mail.tku.edu.tw)

審稿制度：是

國別：USA

出版型式：電子版