出版日期：2012-07-01 00:00:00

著者：Hwang, Jing-Zhong; Wang, Shih-Chieh; Chen, Po-Chen; Huang, Chi-Yuan; Yeh, Jen-Taut; Chen, Kan-Nan

單位：淡江大學化學學系 淡江大學化學工程與材料工程學系

出版者：Dordrecht: Springer Netherlands

著錄名稱、卷期、頁數：Journal of Polymer Research 19(8), 9900(10pages)

摘要：A new UV-curable hydrophilic PU resin was obtained through a green, nonisocyanate, three-reaction process: (1) a bis(cyclic carbonate) (BCC) compound is prepared by inserting carbon dioxide into an epoxy resin (DGEBA) at atmospheric pressure; (2) an amino-terminated hydrophilic PU (NH2-PU) oligomer is obtained through the ring-opening polymerization of BCC utilizing a difunctional amino hydrophilic (polyether) compound such as Jeffamine D-2000; (3) the UV-curable acrylate-PU (UV-PU) prepolymer is obtained as an adduct from the Michael addition of NH2-PU to a diacrylate-terminated compound, 3-acryloyloxy-2-hydroxypropyl methacrylate (AHM). A polyester (PET) textile was treated with this hydrophilic UV-PU prepolymer and then cured by irradiation with UV light. The UV-PU resin was found to crosslink and anchor to the textile fibers after UV irradiation, resulting in a long-lasting hydrophilic surface for the treated textile. The performance properties of the new PU resin on the treated textile were investigated.

關鍵字：Nonisocyanate process; Cyclic carbonate; Hydrophilic; PU; UV curing

語言：en

ISSN：1022-9760; 1572-8935

期刊性質：國外

收錄於：SCI

審稿制度：是

國別：NLD

出版型式：紙本