Evidence of the effect of the apical oxygen on the superconductivity of Y1−xCaxBa2Cu3Oy. An O-1s X-ray absorption spectroscopy study
出版日期:2003-02-01 00:00:00
著者:Hsieh, C. H.; Chang, C.N.; Lee, S. B.; Kao, H.-C. I.; Chin, C. H.
單位:淡江大學化學學系
出版者:Amsterdam: Elsevier BV * North-Holland
著錄名稱、卷期、頁數:Physica C: Superconductivity and its Applications 384(3), pp.314-320
摘要:Two series of Y1-xCaxBa2Cu3Oy, /x=0.05 and 0.10, have been studied by O-1s X-ray absorption near-edge spectroscopy using synchrotron radiation. The characteristics of the decrease of Tc with the decrease of the oxygen content, y, are found different for the series of /x=0.05 and /x=0.10. The former reveals the importance of the holes on the apical oxygen sites. Through a cross examination between these two series of samples, direct evidences are observed that the reduction of the number of holes on the apical oxygen sites has a negative effect on the superconductivity in the underdoped region of Ca-doped YBCO system.
關鍵字:X-ray absorption spectrum;High-Tc superconductor;Y1−xCaxBa2Cu4Oy
語言:en
ISSN:0921-4534
期刊性質:國外
收錄於:SCI
通訊作者:Chang, C. N.
國別:NLD
出版型式:紙本