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Evidence of the effect of the apical oxygen on the superconductivity of Y1−xCaxBa2Cu3Oy. An O-1s X-ray absorption spectroscopy study

類別:期刊論文

學年 / 學期:91-2

出版日期:2003-02-01 00:00:00

著者:Hsieh, C. H.; Chang, C.N.; Lee, S. B.; Kao, H.-C. I.; Chin, C. H.

單位:淡江大學化學學系

出版者:Amsterdam: Elsevier BV * North-Holland

著錄名稱、卷期、頁數:Physica C: Superconductivity and its Applications 384(3), pp.314-320

摘要:Two series of Y1-xCaxBa2Cu3Oy, /x=0.05 and 0.10, have been studied by O-1s X-ray absorption near-edge spectroscopy using synchrotron radiation. The characteristics of the decrease of Tc with the decrease of the oxygen content, y, are found different for the series of /x=0.05 and /x=0.10. The former reveals the importance of the holes on the apical oxygen sites. Through a cross examination between these two series of samples, direct evidences are observed that the reduction of the number of holes on the apical oxygen sites has a negative effect on the superconductivity in the underdoped region of Ca-doped YBCO system.

關鍵字:X-ray absorption spectrum;High-Tc superconductor;Y1−xCaxBa2Cu4Oy

語言:en

ISSN:0921-4534

期刊性質:國外

收錄於:SCI

通訊作者:Chang, C. N.

國別:NLD

出版型式:紙本