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Preparation of NiFe2O4 powder by spray pyrolysis of nitrate aerosols in NH3

類別:期刊論文

學年 / 學期:84-2

出版日期:1996-03-01 00:00:00

著者:Yu, Hsuan-fu; Gandalla, Ahmed M.

單位:淡江大學化學工程與材料工程學系

出版者:New York: Cambridge University Press

著錄名稱、卷期、頁數:Journal of materials research 11(3), pp.663-670

摘要:To avoid the formation of hollow spheres during spray pyrolysis, NH3 was employed to change the mechanism of forming NiFe2O4 from aerosols, containing Ni(II) and Fe(III) nitrates in the required stoichiometric ratio. Nearly spherical, solid submicron NiFe2O4 particles with narrow size distribution were produced in one step using a dilute aqueous solution at pyrolysis temperatures as low as 823 K. However, higher pyrolysis temperatures (≥1023 K) reduced the oxides to metallic alloy of Ni and Fe due to dissociation of NH3. The forming steps and possible reaction mechanisms for aerosol droplets involved in the process were discussed.

語言:en

ISSN:2044-5326 0884-2914

期刊性質:國外

收錄於:EI SCI

國別:USA

出版型式:紙本 電子版