出版日期：1991-04-01 00:00:00

著者：Prentice, Geoffrey; Chang, Yu-chi; Shan, Xuning

單位：淡江大學化學工程與材料工程學系

出版者：Pennington: Electrochemical Society

著錄名稱、卷期、頁數：Journal of the electrochemical society 138(4), pp.890-894

摘要：We have developed a model for the anodic dissolution and passivation of the zinc electrode in alkaline electrolyte. The model is based on postulated elementary reactions. Species on the electrode surface are assumed to follow Langmuir behavior. In previous work we proposed a model for the dissolution kinetics in the prepassive region. In the present investigation we have extended this model to include the passivation process. Using our model, we are able to simulate the general features of the current‐potential behavior. Effects of hydroxide concentration and mass transport rates on current‐potential curves are qualitatively predicted by the model.

關鍵字：electrochemistry; dissolving; passivation; zinc; electrolytes

語言：en

ISSN：0013-4651 1945-7111

期刊性質：國內

出版型式：紙本 電子版