出版日期：2011-06-01 00:00:00

著者：Huang, Kuan-Chieh; Huang, Jen-Hsien; Wu, Chia-Hui; Liu, Chen-Yu; Chen, Hsin-Wei; Chu, Chih-Wei; Lin, Jiann-Tsuen; Lin, Cheng-Lan; Ho, Kuo-Chuan

單位：淡江大學化學工程與材料工程學系

出版者：Cambridge: Royal Society of Chemistry

著錄名稱、卷期、頁數：Journal of Materials Chemistry 21(28), pp.10384-10389

摘要：Nanographite/polyaniline (NG/PANI) composite films were developed and characterized, and the performances of the dye-sensitized solar cells (DSSCs) employing these composite films as the counter electrode (CE) were evaluated in this study. The nanographite/aniline (NG/ANI) particle was firstly synthesized by a reflux method and served as the monomer for the electro-polymerization of the NG/PANI composite films. The surface modification of NG by ANI was confirmed by EDX mapping, TEM image, zeta-potential, and UV-Vis absorption measurements. The electro-polymerized NG/PANI composite films were characterized by Raman spectroscopy, XPS, and conducting-AFM, which verified the successful incorporation of NGs in the PANI films. The electro-catalytic activity of the NG/PANI composite film was evaluated using the positive-feedback mode of scanning electrochemical microscopy (SECM), by which a comparable heterogeneous rate constant (ks0) for the ferrocene/ferrocenium (Fc/Fc+) redox pair was obtained and compared with that of a sputtered Pt. The DSSC employing the NG/PANI (20 mC cm−2) CE exhibited a higher short-circuit current density (JSC) but lower fill factor (FF), and gave a comparable power-conversion efficiency (η) of 7.07%, as compared to that of a DSSC containing a sputtered Pt CE (η = 7.19%).

關鍵字：Sye-sensitized solar cell

語言：en

ISSN：0959-9428

期刊性質：國外

收錄於：SCI

通訊作者：Lin, Cheng-Lan; Ho, Kuo-Chuan

國別：GBR

出版型式：紙本