出版日期：2014-12-01 00:00:00

著者：Lin, Ting-Wei; Chou, Chih-Ming; Lin, Nai-Ti; Lin, Cheng-Lan; Luh, Tien-Yau

單位：淡江大學化學工程與材料工程學系

出版者：Weinheim: Wiley - V C H Verlag GmbH & Co. KGaA

著錄名稱、卷期、頁數：Macromolecular Chemistry and Physics 215(23), pp.2357−2364

摘要：Polynorbornenes with allylic acetoxy terminus are obtained by ring-opening metathesis polymerization of the norbornene derivatives followed by quenching with 1,4-diacetoxy-2Z-butene. Treatment of these polymers with a range of nucleophiles in the presence of a Pd-catalyst gives the corresponding polynorbornenes bearing different end groups. The same protocol is used to modify the end groups of polymeric ladderphanes. Incorporation of an end-group-modified polynorbornene on indium tin oxide (ITO) surface perturbs the electrochemical properties of the ITO electrode.

關鍵字：end‐group modification;ladderphanes;palladium catalysts;polynorbornene;ring‐opening metathesis polymerization

語言：en

ISSN：1521-3935

期刊性質：國外

收錄於：SCI

通訊作者：Luh, Tien-Yau

審稿制度：是

國別：DEU

出版型式：電子版,紙本