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Promoting Photocatalytic Performance of ZnO Particles by Photochemically Reducing Ag+ on the Particle Surfaces

類別:期刊論文

學年 / 學期:103-1

出版日期:2015-01-01 00:00:00

著者:余宣賦; 錢東緯

單位:淡江大學化學工程與材料工程學系

出版者:New York: Taylor & Francis Inc.

著錄名稱、卷期、頁數:Particulate Science and Technology: An International Journal 33(2), pp.197-203

摘要:Dispersive Ag nanoparticles were formed on the surface of crystalline ZnO particles, using a photochemical reduction technique, to produce the Ag/ZnO with high photocatalytic performance. The prepared Ag/ZnO particles, as well as the ZnO particles without Ag attachments, were characterized using x-ray diffractometer, transmission electron microscope, and surface area analyzer. The abilities of the ZnO and the Ag/ZnO particles to photocatalytically decompose methylene blue under 365-nm ultraviolet light irradiation were evaluated by determining the corresponding specific reaction rate constant, k′MB,m (based on the mass of the photocatalyst used). While the ZnO crystalline particles (k′MB,m > 0.43 m3/(kg min)) already possessed better photocatalytic performance than the commercial photocatalyst P25 (k′MB,m = 0.39 m3/(kg min)), the Ag/ZnO particles exhibited much better photocatalytic performance than the ZnO particles. The highest k′MB,m for the Ag/ZnO particles was 1.93 m3/(kg min), which was about five times that of the P25.

關鍵字:Ag deposition; photocatalysis; photochemical reduction; polyol method; zinc oxide

語言:en_US

ISSN:0272-6351

期刊性質:國外

收錄於:SCI EI

通訊作者:Yu, Hsuan-Fu

審稿制度:

國別:USA

出版型式:電子版,紙本