回淡江大學首頁
Sequential Electrochemical Oxidation of Alternating Benzene-Furan Oligomers

類別:期刊論文

學年 / 學期:96-1

出版日期:2007-10-01 00:00:00

著者:Lin,  C.-L. ; Wu, Y.-L.; Chen, C.-L.; Chou, C.-M.; Luh, T.-Y

單位:淡江大學化學工程與材料工程學系

出版者:American Chemical Society

著錄名稱、卷期、頁數:The Journal of Organic Chemistry 72(22), pp.8531-8534

摘要:Electrochemical oxidation of pentaaryl 2 containing two furan moieties occurs sequentially to give diketone 8 after two-electron transfer. Further oxidation with another two-electron transfer gives the corresponding tetraketone 9. Radical cation intermediate is detected by absorption spectroscopy. The radical intermediates of different regiochemistry have been shown to exhibit different oxidation potentials as revealed by the differential pulse voltammetry.

語言:en

ISSN:0022-3263

期刊性質:國外

審稿制度:

國別:USA

出版型式:電子版