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Dual-curing of anionic aqueous-based polyurethanes at ambient temperature

類別:期刊論文

學年 / 學期:86-2

出版日期:1998-02-28 00:00:00

著者:Chen, Guan-Nan; Chen, Kan-nan

單位:淡江大學化學學系

出版者:John Wiley & Sons

著錄名稱、卷期、頁數:Journal of Applied Polymer Science 67(9), pp.1661-1672

摘要:Polyurethane (PU) prepolymers are prepared by a polyaddition of isophorone diisocyanate, polypropylene glycol-1000, and 2,2-dimethylolpropanic acid. The anionic aqueous-based PU dispersions are derived from a water dispersion process of these NCO-terminated PU prepolymers together with a neutralization and a chain extension. They have both terminal amino and pendent carboxylic groups which are potentially reactive sites toward a di-functional epoxy and a tri- or di-aziridinyl compound of a dual-curing PU system, respectively. The stabilities of the resulting PU dispersions on zeta potential and particle size distributions are investigated. The improvements on mechanical, physical, and thermal properties of these dual-cured PU systems are also evaluated.

語言:en

ISSN:0021-8995

期刊性質:國內

審稿制度:

國別:TWN

出版型式:電子版