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NMR spectroscopic studies of dimethyldiethoxy silane hydrolysis and polysiloxane conversion

類別:期刊論文

學年 / 學期:91-1

出版日期:2002-10-10 00:00:00

著者:Tsai, Ming-fu; Lee, Yu-der; Chen, Kan-nan

單位:淡江大學化學學系

出版者:John Wiley & Sons

著錄名稱、卷期、頁數:Journal of Applied Polymer Science 86(2), pp.468-477

摘要:The hydrolysis rate of alkoxy silane (dimethyldiethoxy silane, DMDES, etc.) is a linear relationship vs. the reaction time under the moisture flux control. The hydrolysis process results in formation of the linear polysiloxane products by a subsequent condensation reaction. An amidized alkoxy silane (3-(2-aminoethyl)aminopropylmethyldimethoxy silane, KLM-602 or -aminopropyl- triethoxy silane, -APS) serves as an internal standard of DMDES hydrolysis kinetics measurements. The hydrolysis kinetics of DMDES with the amidized alkoxy silane and the subsequent linear polysiloxanes conversion have been evaluated and characterized by 29Si- and 13C-NMR NMR spectroscopic measurements.

語言:en_US

ISSN:0021-8995

期刊性質:國外

審稿制度:

國別:USA

出版型式:紙本