出版日期：2001-01-24 00:00:00

著者：Huang, Woei-kae; Yeh, Jen-taut; Chen, Kwei-Ju; Chen, Kan-nan

單位：淡江大學化學學系

出版者：John Wiley & Sons

著錄名稱、卷期、頁數：Journal of Applied Polymer Science 79(4), pp.662-673

摘要：Aziridinyl phosphazene (NPAZ) was introduced to aqueous-based polyurethane (PU) as a flame retardant and a postcuring agent, mainly because of the presence of phosphorus compositions, as well as the reactive aziridinyl groups on NPAZ. This dual-function NPAZ was prepared from the substitution reaction of hexachlorocyclotriphosphazene with aziridine. Aqueous-based PU was treated with NPAZ and its curing reaction took place upon drying. The performance properties of this NPAZ cured PU (NPAZ-PU) were improved and better than those of the original PU. The phosphorus composition from NPAZ was evenly distributed on this NPAZ-PU film, which was identified by the phosphorus mapping on the energy dispersion spectrum. The physical and mechanical properties of NPAZ-PU were evaluated by the measurements of the gel content, water uptake, ethanol swelling, and tensile stress. The thermal properties of NPAZ-PU were investigated by thermogravimetric analysis (TGA), TG analyzer-interfaced FTIR, and dynamic mechanical thermal analysis. Furthermore, its combustion behaviors were demonstrated with the data of a cone calorimeter measurement.

語言：en

ISSN：0021-8995

期刊性質：國內

審稿制度：否

國別：TWN

出版型式：電子版