Anomalous Pr ordering and structural analysis for oxygenated tetragonal 1212 compound Pr1.5Ba1.5Cu3O7.2
出版日期:1999-11-01 00:00:00
著者:Ku, H. C.; Luo, H. M.; Chi, Y. P.; Lin, B. N.; Hsu, Y. Y.; Lee, T. J.; Shi, J. B.; 高惠春; Kao, H. C. I.
單位:淡江大學化學學系
出版者:Springer
著錄名稱、卷期、頁數:Journal of low temperature physics 117(3-4), pp.885-890
摘要:Magnetic measurement and powder X-ray Rietveld analysis are performed on oxygenated Pr1.5Ba1.5Cu3O7.2cuprate. This tetragonal compound with lattice parameters a = 0.38916 nm and c = 1.16177 nm is found to form the TlBa2CaCu2O71212-type structure when written as Cu[Ba1.5Pr0.5]PrCu2O7.2. Low temperature magnetic data indicate that anomalous Pr order temperature TN(Pr) decreases from 18 K for orthorhombic PrBa2Cu3O6.9to 10.5 K for Pr1.5Ba1.5Cu3O7.2. The increasing Pr-O bond length with decreasing TNindicates that Pr ordering is closely correlated with the wave function overlap between Pr-4f orbital and O-2pπorbital in the CuO2bi-layers.
語言:en
ISSN:0022-2291
期刊性質:國內
審稿制度:否
國別:TWN
出版型式:電子版