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A novel potassium ion sensing based on Prussian blue thin films

類別:期刊論文

學年 / 學期:89-2

出版日期:2001-06-01 00:00:00

著者:林正嵐; Ho, K.-C.

單位:淡江大學化學工程與材料工程學系

著錄名稱、卷期、頁數:Sensors and Actuators B: Chemical 76(1-3), pp.512-518

摘要:A novel method for sensing potassium ions in aqueous solutions is presented. This method is based on the Prussian blue (PB) modified tin oxide (TO) electrode. Thin films of PB (KFeFe(CN)6), deposited onto transparent TO substrate, are reduced to Everitt’s salt (ES, or K2FeFe(CN)6) in solutions containing potassium ions. Using an in situ measurement of the absorbance changes in PB thin film while applying different reductive potentials to the electrode, the PB mole fraction within the thin film, x, can be obtained for solutions containing various concentrations of potassium ions. By applying either the theory of regular solution (0.25

關鍵字:Prussian blue;Potassium ion sensing;Margules equation;Regular solution;Modified electrode

語言:en

ISSN:0925-4005 1873-3077

期刊性質:國外

收錄於:SCI EI

審稿制度:

國別:NLD

出版型式:電子版,紙本