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Preparation and characterization of spironaphthooxazine/polyacrylate photochromic hard coatings on plastic substrates

類別:期刊論文

學年 / 學期:102-2

出版日期:2014-06-01 00:00:00

著者:Chang, Chao-Ching; Wang, Chih-Shing; Chen, Yu-Chen; Cheng, Liao-Ping

單位:淡江大學化學工程與材料工程學系 能源與光電材料研究中心

出版者:Taiwan: Tamkang University Press

著錄名稱、卷期、頁數:Journal of Applied Science and Engineering 17(2), p.167-174

摘要:Optical coatings exhibiting photochromic effects were prepared by UV-curing of a coating formulation that incorporates a hexa-functional monomer, DPHA, and an organic dye, spironaphthooxazine. Spectroscopic studies of the coatings indicated efficient photochromic activities in response to UV irradiation. The depth of color and the rate of bleaching at 610 nm were found to depend on the UV dosage and the dye content; specifically, the transmittance returned from 42 to 82% and from 38 to 67% in 60 s. for the coating containing 3.7 wt% dye that received 0.45 and 3.6 of J/cm2 of UV exposure, respectively. Furthermore, the coatings were very hard (7H, pencil hardness) and adhered perfectly (100%, peel test) on poly (methyl methacrylate) substrates.

關鍵字:Photochromic;Coatings;Spirooxazine;Polyacrylate

語言:en_US

ISSN:1560-6686

期刊性質:國內

收錄於:EI

通訊作者:Cheng, Liao-Ping

審稿制度:

國別:TWN

出版型式:紙本