出版日期：2015-12-01 00:00:00

著者：Chang, Chao-Ching; Lin, Zi-Min; Huang, Shu-Hui; Cheng, Liao-Ping

著錄名稱、卷期、頁數：Journal of applied science and engineering 18(4), p.387-394

摘要：Silica nanoparticles synthesized from tetraethoxysiliane (TEOS) via a sol-gel process were surface-modified by using 3-(trimethoxysilyl)propyl methacrylate (MSMA) and 1H, 1H, 2H, 2H- perfluorooctyltriethoxysilane (13F). MSMA acted as a coupling agent and a C=C provider, whereas 13F was employed to enhance hydrophobicity. The surface-modified silica particles together with a multi-functional monomer were UV-cured to yield highly transparent thin films (~7 μm) on plastic substrates. Both FE-SEM imaging and UV-visible spectroscopy confirmed uniform dispersion of nano-silica in the hybrid thin films. The coating surfaces were extremely smooth, with average roughness over the range 1.0-2.3 nm based on profilometric measurements. X-ray photoelectron spectroscopy indicated that surface-modified silica particles have migrated to the top surface to reduce the surface energy. Therefore, only a small dosage of 1 mol% (vs. TEOS) was enough to engender surface hydrophobicity with water contact angle of 100°. Furthermore, all of the prepared coatings were hard with pencil hardness reached 6H, and they adhered strongly to the poly(methyl methacrylate) substrate according to the peel test.

關鍵字：Colloidal Silica; Hard Coating;UV-curing;Plastic Substrate;Hydrophobic

語言：en

ISSN：1560-6686

期刊性質：國內

收錄於：EI

審稿制度：是

國別：TWN

出版型式：電子版